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Synthesis and application of phosphorus dendrimer immobilized azabis(oxazolines)

Gissibl, A. ; Padie, C. ; Hager, M. ; Jaroschik, F. ; Rasappan, R. ; Cuevas-Yanez, E. ; Turrin, C. O. ; Caminade, A. M. ; Majoral, J. P. ; Reiser, O.



Abstract

Phosphorus dendrimer immobilized azabis(oxazoline) ligands can be efficiently synthesized up to the third generation with 48 ligand molecules being attached to the periphery using click chemistry. The so-assembled macromolecules were evaluated in copper(II)-catalyzed asymmetric benzoylations, showing good yields and enantioselectivities. Moreover, the copper(II)-catalysts could be readily ...

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