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Rhodium-Based Metal–Organic Polyhedra Assemblies for Selective CO2 Photoreduction

Ghosh, Ashta C. ; Legrand, Alexandre ; Rajapaksha, Rémy ; Craig, Gavin A. ; Sassoye, Capucine ; Balázs, Gábor ; Farrusseng, David ; Furukawa, Shuhei ; Canivet, Jérôme ; Wisser, Florian M.


Heterogenization of molecular catalysts via their immobilization within extended structures often results in a lowering of their catalytic properties due to a change in their coordination sphere. Metal-organic polyhedra (MOP) are an emerging class of well-defined hybrid compounds with a high number of accessible metal sites organized around an inner cavity, making them appealing candidates for ...


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