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One-dimensional diffuse scattering of 1,3-di(tert-butyl)cyclopentadienyl pentaphosphaferrocene modelled with closed-form expressions

Stöger, Berthold ; Peresypkina, Eugenia ; Virovets, Alexander



Abstract

1,3-di(tert-butyl)cyclopentadienyl pentaphosphaferrocene (Cp '' FeP5) crystallizes as polytypes, where adjacent layers are related by either a c- or an nglide reflection. In the simplest possible polytypes only one kind of glide reflections is realized, leading to overall Pca2(1) or Pna2(1) symmetry respectively. Crystals isolated from the same crystallization experiment feature a varying degree ...

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