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Coordination polymers and molecular complexes of group 13 metal halides with bis-pyridylethane: comparison with rigid N-containing ligands

Gugin, Nikita Y. ; Virovets, Alexander V. ; Peresypkina, Eugenia ; Davydova, Elena I. ; Timoshkin, Alexey Y.



Abstract

A systematic structural study of novel complexes formed by aluminium and gallium trihalides with 1,2-bis(4-pyridyl)ethane (bpa) is performed. The complexes were synthesized using a solvent-free melt reaction approach and crystallized by sublimation in vacuum. Ionic coordination polymers (CPs) [MCl2(bpa)(2)](+)[MCl4](-), M = Al (1) or Ga (2), exhibit isostructural one-dimensional networks. Ionic ...

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