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Copper Photocatalyzed Divergent Access to Organic Thio- and Isothiocyanates

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Abderrazak, Youssef ; Reiser, Oliver
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Date of publication of this fulltext: 17 May 2024 15:14


We disclose a copper-photocatalyzed strategy that enables selective access to organic thiocyanates and isothiocyanates using benzylic thiocyanates as ATRA reagents. The electronic nature of the aromatic system is a crucial factor defining the outcome of the reaction for forging either the kinetic C–S or the thermodynamic C–N bonds. Mechanistic investigations support a radical pathway initiated by ...


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