Copper Photocatalyzed Divergent Access to Organic Thio- and Isothiocyanates

URN to cite this document:: urn:nbn:de:bvb:355-epub-582864
DOI to cite this document:: 10.5283/epub.58286

Abderrazak, Youssef ; Reiser, Oliver

License: Creative Commons Attribution 4.0
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Date of publication of this fulltext: 17 May 2024 15:14

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Abstract

We disclose a copper-photocatalyzed strategy that enables selective access to organic thiocyanates and isothiocyanates using benzylic thiocyanates as ATRA reagents. The electronic nature of the aromatic system is a crucial factor defining the outcome of the reaction for forging either the kinetic C–S or the thermodynamic C–N bonds. Mechanistic investigations support a radical pathway initiated by ...