![[img]](https://epub.uni-regensburg.de/style/images/fileicons/application_zip.png) Primary research data for the photocatalytic dehydration of 1-aryl-1,2-ethanediols | Data Download ( ZIP Archive | 456MB) |
Data archive of "Photocatalytic dehydration of 1-aryl-1,2-ethanediols to methyl ketones via HAT-initiated spin-center shift"
Taskinen, Elina K.
, Kolb, Daniel , Morgenstern, Martin and König, Burkhard
(2024)
Data archive of "Photocatalytic dehydration of 1-aryl-1,2-ethanediols to methyl ketones via HAT-initiated spin-center shift".
[Dataset]
Date of publication of this fulltext: 18 Jul 2024 06:35
Dataset
DOI to cite this document: 10.5283/epub.58645
Abstract
Herein, we report a photocatalytic redox-neutral dehydration of native aryl-1,2-ethanediols to aryl methyl ketones. This mild reaction can be realized with a single organic photocatalyst and yields water as the sole by-product. Mechanistic studies suggest the product formation via a sequence of HAT / 1,2-spin-center shift (SCS) catalyzed by highly active mixture stemming from Eosin Y.
Involved Institutions
Details
| Item type | Dataset |
| Date | July 2024 |
| Institutions | Chemistry and Pharmacy > Institut für Organische Chemie Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König |
| Keywords | Photocatalysis, dehydration, Eosin Y degradation |
| Dewey Decimal Classification | 500 Science > 500 Natural sciences & mathematics 500 Science > 540 Chemistry & allied sciences |
| Status | Unpublished |
| Refereed | No, this document will not be refereed |
| Created at the University of Regensburg | Yes |
| URN of the UB Regensburg | urn:nbn:de:bvb:355-epub-586457 |
| Item ID | 58645 |
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