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Zizlsperger, Martin ; Nerreter, Svenja ; Yuan, Q. ; Lohmann, K. B. ; Sandner, Fabian ; Schiegl, Felix ; Meineke, Christian ; Gerasimenko, Yaroslav A. ; Herz, L. M. ; Siday, Thomas ; Huber, Markus A. ; Johnston, M. B. ; Huber, Rupert

In situ nanoscopy of single-grain nanomorphology and ultrafast carrier dynamics in metal halide perovskites

Zizlsperger, Martin , Nerreter, Svenja , Yuan, Q., Lohmann, K. B., Sandner, Fabian, Schiegl, Felix , Meineke, Christian , Gerasimenko, Yaroslav A. , Herz, L. M., Siday, Thomas , Huber, Markus A. , Johnston, M. B. und Huber, Rupert (2024) In situ nanoscopy of single-grain nanomorphology and ultrafast carrier dynamics in metal halide perovskites. Nature Photonics.

Veröffentlichungsdatum dieses Volltextes: 01 Aug 2024 08:57
Artikel
DOI zum Zitieren dieses Dokuments: 10.5283/epub.58756


Zusammenfassung

Designing next-generation light-harvesting devices requires a detailed understanding of the transport of photoexcited charge carriers. The record-breaking efficiencies of metal halide perovskite solar cells have been linked to effective charge-carrier diffusion, yet the exact nature of charge-carrier out-of-plane transport remains notoriously difficult to explain. The characteristic spatial ...

Designing next-generation light-harvesting devices requires a detailed understanding of the transport of photoexcited charge carriers. The record-breaking efficiencies of metal halide perovskite solar cells have been linked to effective charge-carrier diffusion, yet the exact nature of charge-carrier out-of-plane transport remains notoriously difficult to explain. The characteristic spatial inhomogeneity of perovskite films with nanograins and crystallographic disorder calls for the simultaneous and hitherto elusive in situ resolution of the chemical composition, the structural phase and the ultrafast dynamics of the local out-of-plane transport. Here we simultaneously probe the intrinsic out-of-plane charge-carrier diffusion and the nanoscale morphology by pushing depth-sensitive terahertz near-field nanospectroscopy to extreme subcycle timescales. In films of the organic–inorganic metal halide perovskite FA0.83Cs0.17Pb(I1−xClx)3 (where FA is formamidinium), domains of the cubic α-phase are clearly distinguished from the trigonal δ-phase and PbI2 nano-islands. By analysing deep-subcycle time shifts of the scattered terahertz waveform after photoexcitation, we access the vertical charge-carrier dynamics within single grains. At all of the measured locations, despite topographic irregularities, diffusion is surprisingly homogeneous on the 100 nm scale, although it varies between mesoscopic regions. Linking in situ carrier transport with nanoscale morphology and chemical composition could introduce a paradigm shift for the analysis and optimization of next-generation optoelectronics that are based on nanocrystalline materials.



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  • [img] [img] Zizlsperger, Martin , Nerreter, Svenja , Yuan, Q., Lohmann, K. B., Sandner, Fabian, Schiegl, Felix , Meineke, Christian , Gerasimenko, Yaroslav A. , Herz, L. M., Siday, Thomas , Huber, Markus A. , Johnston, M. B. und Huber, Rupert (2024) In situ nanoscopy of single-grain nanomorphology and ultrafast carrier dynamics in metal halide perovskites. Nature Photonics. [Gegenwärtig angezeigt]

Details

DokumentenartArtikel
Titel eines Journals oder einer ZeitschriftNature Photonics
Datum17 Juli 2024
InstitutionenPhysik > Institut für Experimentelle und Angewandte Physik > Lehrstuhl Professor Huber > Arbeitsgruppe Rupert Huber
Identifikationsnummer
WertTyp
10.1038/s41566-024-01476-1DOI
Dewey-Dezimal-Klassifikation500 Naturwissenschaften und Mathematik > 530 Physik
StatusVeröffentlicht
BegutachtetJa, diese Version wurde begutachtet
An der Universität Regensburg entstandenZum Teil
URN der UB Regensburgurn:nbn:de:bvb:355-epub-587567
Dokumenten-ID58756

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