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Abstract
The authors demonstrate in a spectroscopic expt. the hybridization of rotor states within the X and A electronic states of ICl, induced by parallel magnetic and elec. fields of up to 0.7 T and 50 kV/cm. For a polar paramagnetic electronic state, such as the A state, the elec. and magnetic fields conjoin in producing hybridization for one half of the mol. ensemble while they counteract for the ...
Abstract
The authors demonstrate in a spectroscopic expt. the hybridization of rotor states within the X and A electronic states of ICl, induced by parallel magnetic and elec. fields of up to 0.7 T and 50 kV/cm. For a polar paramagnetic electronic state, such as the A state, the elec. and magnetic fields conjoin in producing hybridization for one half of the mol. ensemble while they counteract for the other half. In the latter case the elec. and magnetic effects can be tuned to balance out exactly; the concomitant field-induced hyperfine splitting remains in place, however, despite the resulting free rotation of the mol.
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