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Electric Linear Dichroism with a Simple Interpretation in Terms of Molecular Pendular States
Slenczka, A. (1998) Electric Linear Dichroism with a Simple Interpretation in Terms of Molecular Pendular States. Physical Review Letters 80 (12), S. 2566-2569.Veröffentlichungsdatum dieses Volltextes: 05 Aug 2009 13:51
Artikel
DOI zum Zitieren dieses Dokuments: 10.5283/epub.6072
Zusammenfassung
An anisotropic orientation of the figure axis of elec. dipolar ICl is forced by a strong homogeneous elec. field. The mol. is transferred into a pendular state and shows optical anisotropy due to the body fixed mol. transition dipole moment. This holds in exactly the same way for magnetically dipolar mols. in a homogeneous magnetic field. A simple geometric model is applied which simulates all ...
An anisotropic orientation of the figure axis of elec. dipolar ICl is forced by a strong homogeneous elec. field. The mol. is transferred into a pendular state and shows optical anisotropy due to the body fixed mol. transition dipole moment. This holds in exactly the same way for magnetically dipolar mols. in a homogeneous magnetic field. A simple geometric model is applied which simulates all spectral features quant. without any fitting procedure for both the elec. and the magnetic case. The sparse structure of polarization spectra of such a sample allows for easy reading of spectroscopic consts. and study of electronic states of even large mols.
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| Dokumentenart | Artikel | ||||
| Titel eines Journals oder einer Zeitschrift | Physical Review Letters | ||||
| Band: | 80 | ||||
|---|---|---|---|---|---|
| Nummer des Zeitschriftenheftes oder des Kapitels: | 12 | ||||
| Seitenbereich: | S. 2566-2569 | ||||
| Datum | 1998 | ||||
| Zusätzliche Informationen (Öffentlich) | CAN 128:263299; 73-2; Optical, Electron, and Mass Spectroscopy and Other Related Properties; 7790-99-0 (Iodine chloride (ICl) Role: PRP (Properties) (elec. linear dichroism with a simple interpretation in terms of mol. pendular states) | ||||
| Institutionen | Chemie und Pharmazie > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry III - Physical Chemistry (Molecular Spectroscopy and Photochemistry) > Prof Dr. Alkwin Slenczka | ||||
| Identifikationsnummer |
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| Stichwörter / Keywords | Electrooptical effect; Electrooptical effect (dichroism, elec. linear dichroism with a simple interpretation in terms of mol. pendular states); Energy level (elec. linear dichroism with a simple interpretation in terms of mol. pendular states); Dichroism; Dichroism (elec., elec. linear dichroism with a simple interpretation in terms of mol. pendular states); iodine chloride elec linear dichroism; mol pendular state iodine chloride dichroism | ||||
| Dewey-Dezimal-Klassifikation | 500 Naturwissenschaften und Mathematik > 540 Chemie | ||||
| Status | Veröffentlicht | ||||
| Begutachtet | Ja, diese Version wurde begutachtet | ||||
| An der Universität Regensburg entstanden | Ja | ||||
| URN der UB Regensburg | urn:nbn:de:bvb:355-epub-60728 | ||||
| Dokumenten-ID | 6072 |
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