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Slenczka, A.

Electric Linear Dichroism with a Simple Interpretation in Terms of Molecular Pendular States

Slenczka, A. (1998) Electric Linear Dichroism with a Simple Interpretation in Terms of Molecular Pendular States. Physical Review Letters 80 (12), S. 2566-2569.

Veröffentlichungsdatum dieses Volltextes: 05 Aug 2009 13:51
Artikel
DOI zum Zitieren dieses Dokuments: 10.5283/epub.6072


Zusammenfassung

An anisotropic orientation of the figure axis of elec. dipolar ICl is forced by a strong homogeneous elec. field. The mol. is transferred into a pendular state and shows optical anisotropy due to the body fixed mol. transition dipole moment. This holds in exactly the same way for magnetically dipolar mols. in a homogeneous magnetic field. A simple geometric model is applied which simulates all ...

An anisotropic orientation of the figure axis of elec. dipolar ICl is forced by a strong homogeneous elec. field. The mol. is transferred into a pendular state and shows optical anisotropy due to the body fixed mol. transition dipole moment. This holds in exactly the same way for magnetically dipolar mols. in a homogeneous magnetic field. A simple geometric model is applied which simulates all spectral features quant. without any fitting procedure for both the elec. and the magnetic case. The sparse structure of polarization spectra of such a sample allows for easy reading of spectroscopic consts. and study of electronic states of even large mols.



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Details

DokumentenartArtikel
Titel eines Journals oder einer ZeitschriftPhysical Review Letters
Band:80
Nummer des Zeitschriftenheftes oder des Kapitels:12
Seitenbereich:S. 2566-2569
Datum1998
Zusätzliche Informationen (Öffentlich)CAN 128:263299; 73-2; Optical, Electron, and Mass Spectroscopy and Other Related Properties; 7790-99-0 (Iodine chloride (ICl) Role: PRP (Properties) (elec. linear dichroism with a simple interpretation in terms of mol. pendular states)
InstitutionenChemie und Pharmazie > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry III - Physical Chemistry (Molecular Spectroscopy and Photochemistry) > Prof Dr. Alkwin Slenczka
Identifikationsnummer
WertTyp
1998:183309Andere
Stichwörter / KeywordsElectrooptical effect; Electrooptical effect (dichroism, elec. linear dichroism with a simple interpretation in terms of mol. pendular states); Energy level (elec. linear dichroism with a simple interpretation in terms of mol. pendular states); Dichroism; Dichroism (elec., elec. linear dichroism with a simple interpretation in terms of mol. pendular states); iodine chloride elec linear dichroism; mol pendular state iodine chloride dichroism
Dewey-Dezimal-Klassifikation500 Naturwissenschaften und Mathematik > 540 Chemie
StatusVeröffentlicht
BegutachtetJa, diese Version wurde begutachtet
An der Universität Regensburg entstandenJa
URN der UB Regensburgurn:nbn:de:bvb:355-epub-60728
Dokumenten-ID6072

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