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Determination of the electric dipole moment of ICl(B3P0) from pendular spectra

Slenczka, Alkwin, Friedrich, Bretislav and Herschbach, Dudley (1994) Determination of the electric dipole moment of ICl(B3P0) from pendular spectra. Chemical Physics Letters 224 (3-4), pp. 238-42.

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The authors evaluate the elec. dipole moment of an excited electronic state of ICl(B, v = 0) from transitions within the B, 0<-X, 2 band that take place between pendulum/pinwheel states hybridized by a strong elec. field (up to 15kV/cm). The authors find mB = 1.41(+-0.05) D, with Cl more neg. than I as in the ground electronic state.

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Item type:Article
Additional Information (public):CAN 121:146014; 76-1; Electric Phenomena; 7790-99-0 (Iodine chloride (icl) Role: PRP (Properties) (elec. dipole moment of)
Institutions:Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry III - Physical Chemistry (Molecular Spectroscopy and Photochemistry) > Prof. Dr. Alkwin Slenczka
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Keywords:Dipole moment (of iodine chloride); Fluorescence (laser-induced, from iodine chloride); elec dipole moment iodine chloride; pendular spectra laser induced fluorescence
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:No
Item ID:6076
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