Paramagnetic Redox Stages of a Bisphane: An ESR and ENDOR Study

URN to cite this document:: urn:nbn:de:bvb:355-epub-61513
DOI to cite this document:: 10.5283/epub.6151

Gerson, Fabian ; König, Burkhard ; Scholz, Michael ; Meijere, Armin de

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Date of publication of this fulltext: 05 Aug 2009 13:51

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Abstract

Seven redox stages, the dication 12+, the radical cation , the neutral 1, the radical anion , the dianion 12-, the radical trianion , and the tetraanion 14-, are indicated by cyclic voltammetry for the bisphane 1, in which the benzene decks of two lateral paracyclophane moieties are orthogonal to the plane of anthracene framework. In and , the unpaired electron is accommodated into the central ...