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Urea Derivatives of 1,4,7,10-Tetraazacyclododecane: Synthesis and Binding Properties

König, B. ; Pelka, M. ; Subat, M. ; Dix, I. ; Jones, P. G.



Zusammenfassung

The reaction between 1,4,7,10-tetraazacyclododecane (cyclen) and partially protected derivatives and isocyanates gives macrocyclic ureas in good yields. Bridged biscyclens with aliphatic or aromatic spacers were obtained from the reaction between diisocyanates and partially protected cyclen. The substituted cyclen derivatives with one or two urea moieties coordinate zinc(II) and copper(II) ions ...

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