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Synthesis of functionalized fluorescent europium(III) terpyridyl chelates

Kozhevnikov, V. N. ; Kozhevnikov, D. N. ; Rusinov, V. L. ; Chupakhin, O. N. ; König, B.


The synthesis of substituted terpyridines via triazine intermediates is described. The intermediates allow the facile introduction of cyano groups, which are converted into amino diacetic acid moieties. Together with the terpyridine nitrogen atoms they shield coordinated europium(III) ions completely from the solvent. The terpyridines may be further functionalized for specific applications using ...


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