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A Synthetic Creatinine Receptor: Imprinting of a Lewis-Acidic Zinc(II)cyclen Binding Site to Shape its Molecular Recognition Selectivity

Subat, M. ; Borovik, A. S. ; König, B.


Molecularly imprinted polymers (MIPs) from polymerizable Lewis acidic zinc(II)cyclen complexes and ethylene glycol dimethyl acrylate have been prepared. For the imprinting process the template molecule creatinine is reversibly coordinated to the zinc atom. The high strength of this interaction allows analyte binding to the MIP from aqueous solution with high affinity. Its pH dependence is used ...


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