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Luminescent Crown Ether Amino Acids - Selective Binding to N-terminal Lysine in Peptides

Mandl, C. P. ; König, B.


Crown ether amino acids (CEAAs) with a luminescent phthalic ester or phthalimide moiety have been prepared. Simple peptide chemistry covalently tethers the macrocycles to give ditopic ammonium-ion binders. The binding events of both crown ether groups are monitored independently by changes of their specific emission properties. The affinity of the bis-CEAA to bis-ammonium ions is distance ...


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