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Chiral NADH Model Systems functionalized with Zn(II)-cyclen as Flavin Binding Site

Ritter, S. ; Eiblmeier, M. ; Michlova, V. ; König, B.



Abstract

A series of chiral peptides has been prepared, bearing a 1,4-dihydronicotine amide and a zinc cyclen moiety. The metal complex reversibly binds flavins in aqueous solution, while the dihydronicotine amide serves as a NADH model transferring a hydride to the flavin within the assembly. The reaction rate of the redox reaction was monitored and determined by UV spectroscopy. The reaction rates of ...

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