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Synthesis and Structure of Chiral Methoxypyrrole Amino Acids (MOPAS)

Bonauer, C. and König, B. (2005) Synthesis and Structure of Chiral Methoxypyrrole Amino Acids (MOPAS). Synthesis, 2367 - 2372.

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A methoxypyrrole amino acid (MOPAS) resembling the structure of H2N-Val-Δ-Ala-OEt in β-sheet conformation has been prepared by a chiral auxiliary approach. The X-ray structure analysis confirms the absolute configuration of the dipeptide mimic. Standard peptide coupling procedures allow coupling of the chiral MOPAS with natural amino acids or their extension by additional MOPAS units. A tight ...


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Item type:Article
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König
Projects:GRK 760, Graduiertenkolleg Medizinische Chemie
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Keywords:heterocycles - amino acids - peptides - chiral auxiliaries - imines
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:6258
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