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Solid Phase Synthesis of Metal-Complex containing Peptides

Dirscherl, G. ; Knape, R. ; Hanson, P. ; König, B.


We report the synthesis of Fmoc protected single amino acid chelates (SAAC) and their metal complexes. The modified amino acids are suitable for solid-phase peptide synthesis. The use of 4-hydroxymethylbenzoic acid AM (HMBA-AM) resin allows the nucleophilic cleavage of the peptide–metal complexes from the resin without decomplexation.

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