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Utilizing Reversible Copper(II) Peptide Coordination in a Sequence Selective Luminescent Receptor

Stadlbauer, S. ; Riechers, A. ; Späth, A. ; König, B.



Abstract

Although vast information about the coordination ability of amino acids and peptides to metal ions is available, little use of this has been made in the rational design of selective peptide receptors. We have combined a copper(II) nitrilotriacetato (NTA) complex with an ammonium-ion-sensitive and luminescent benzocrown ether. This compound revealed micromolar affinities and selectivities for ...

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