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Synthesis And Characterization Of 1-(2H-tetrazol-5-YL)-1,4,7,10-tetraazacyclododecane And Its Zn(II), Ni(II), AND Cu(II) complexes

Woinaroschy, K. ; Ursu, A. ; König, B.


Abstract

As part of an ongoing effort to develop new metal complexes of tetraazamacrocycles with novel properties in coordination or functionalization we report here the synthesis of a new derivative of 1,4,7,10-tetraazacyclododecane (cyclen) with a tetraazole moiety directly bound to the azamacrocycle. The new ligand was obtained by reaction with cyanogen bromide giving the cyanamide, followed by a [2+3] ...

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