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Acceleration of Suzuki-Miyaura- and Stille-type coupling reactions by near UV-A light irradiation

Imperato, G. ; König, B.



Abstract

Irradiation of a palladium catalyst bearing UV-A-absorbing phosphine ligands with low-intensity UV-A light leads to higher conversions of reactants at lower temperatures and an increased selectivity towards the cross-coupling product in Suzuki-Miyaura- and Stille-type reactions. The examples studied illustrate that a selective energy input into the catalyst by irradiation leads to more selective ...

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