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Macrocyclic receptor for pertechnetate and perrhenate anions

Kolesnikov, Grigory V. ; German, Konstantin E. ; Kirakosyan, Gayane ; Tananaev, Ivan G. ; Ustynyuk, Yuri A. ; Khrustalev, Victor N. ; Katayev, Evgeny A.



Abstract

The design and synthesis of a neutral macrocyclic host that is capable of perrhenate and pertechnetate recognition is described. The anion affinities and underlying coordination modes were estimated by several experimental and theoretical methods including a new technique-reverse Tc-99 NMR titration.


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