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Synthesis of Cyclometallated Platinum Complexes with Substituted Thienylpyridines and Detailed Characterization of Their Luminescence Properties

Kozhevnikov, D. N. ; Kozhevnikov, V. N. ; Ustinova, M. M. ; Santoro, A. ; Bruce, D. W. ; König, Burkhard ; Czerwieniec, R. ; Fischer, T. ; Zabel, Manfred ; Yersin, Hartmut


Synthesis of various derivatives of 2-(2-thienyl)pyridine via substituted 3-thienyl-1,2,4-triazines is reported. The final step of the synthesis is a transformation of the triazine ring to pyridine in an aza-Diels−Alder-type reaction. The resulting 5-aryl-2-(2-thienyl)pyridines (HL1-HL4) and 5-aryl-2-(2-thienyl)cyclopenteno[c]pyridines (HL5-HL8) (with aryl = phenyl, 4-methoxyphenyl, 2-naphtyl, ...


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