Low-Temperature Synthesis of Diamminesodium(1+) Triamminesodium(1+) Trithioantimonate(3−) Ammoniate (1 : 2 : 1 : 2) ([Na(NH3)3]2[Na(NH3)2]SbS3⋅2 NH3), A Solvated Neutral Sodium Trithioantimonate(3−) (3 : 1) Na3SbS3) Ion Complex

Korber, Nikolaus ; Richter, Frank

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Details

Item type:	Article
Journal or Publication Title:	Helvetica Chimica Acta
Publisher:	WILEY-V C H VERLAG GMBH
Place of Publication:	BERLIN
Volume:	84
Number of Issue or Book Chapter:	8
Page Range:	pp. 2368-2372
Date:	2001
Institutions:	Chemistry and Pharmacy > Institut für Anorganische Chemie
Identification Number:	Value Type 10.1002/1522-2675(20010815)84:8<2368::AID-HLCA2368>3.0.CO;2-D DOI
Keywords:	;
Dewey Decimal Classification:	500 Science > 540 Chemistry & allied sciences
Status:	Published
Refereed:	Yes, this version has been refereed
Created at the University of Regensburg:	Yes
Item ID:	73907

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Abstract

A solution of sodium in liquid ammonia reacts with Sb2S3 to form large colorless crystals of the composition Na3SbS3. 10 NH3. The trigonal-pyramidal SbS33- anion is ion-paired with three Na+ counter ions, the coordination spheres of which are completed by eight ammine ligands. The resulting neutral [Na(NH3)(3)](2)-[Na(NH3)(2)]SbS3 Molecules crystallize together with two ammonia molecules of ...

Abstract

A solution of sodium in liquid ammonia reacts with Sb2S3 to form large colorless crystals of the composition Na3SbS3. 10 NH3. The trigonal-pyramidal SbS33- anion is ion-paired with three Na+ counter ions, the coordination spheres of which are completed by eight ammine ligands. The resulting neutral [Na(NH3)(3)](2)-[Na(NH3)(2)]SbS3 Molecules crystallize together with two ammonia molecules of solvation in the space group P2(1)/c (a = 9.828(2), b = 6.0702(4), c = 33.4377(6) Angstrom, beta = 91.362(7)degrees, V= 1994.2(5) Angstrom (3), Z = 4).

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