Abstract
Conductivity data of sodium chloride in binary mixtures of water and 1,4-dioxane from 5 to 35 degrees C were measured, covering an electrolyte concentration range up to the limit of solubility in the solvent mixtures and up to 5 mol-dm(-3) in pure water. Data analysis is based on the mean spherical approximation (MSA). Comparison is made with the data representation by the empirical Casteel-Amis ...
Abstract
Conductivity data of sodium chloride in binary mixtures of water and 1,4-dioxane from 5 to 35 degrees C were measured, covering an electrolyte concentration range up to the limit of solubility in the solvent mixtures and up to 5 mol-dm(-3) in pure water. Data analysis is based on the mean spherical approximation (MSA). Comparison is made with the data representation by the empirical Casteel-Amis equation. The association constants of the MSA are compared with those from chemical model calculations at low concentrations (lcCM).
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