The Elusive Ternary Intermediates of Chiral Phosphoric Acids in Ion Pair Catalysis─Structures, Conformations, and Aggregation

URN to cite this document:: urn:nbn:de:bvb:355-epub-746027
DOI to cite this document:: 10.5283/epub.74602

Franta, Maximilian ; Pattanaik, Aryaman ; Silva, Wagner

; Motiram-Corral, Kumar

; Rehbein, Julia

; Gschwind, Ruth M.

License: Creative Commons Attribution 4.0
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Date of publication of this fulltext: 14 Jan 2025 06:49

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Abstract

In ion-pair catalysis, the last intermediate structures prior to the stereoselective transition states are of special importance for predictive models due to the high isomerization barrier between E- and Z-substrate double bonds connecting ground and transition state energies. However, in prior experimental investigations of chiral phosphoric acids (CPA) solely the early intermediates could be ...