Where Does the Proton Go? Structure and Dynamics of Hydrogen‐Bond Switching in Aminophosphine Chalcogenides

URN to cite this document:: urn:nbn:de:bvb:355-epub-749478
DOI to cite this document:: 10.5283/epub.74947

Huber, Tanja

; Mayer, Gabriel ; Kümper, Manuel ; Silva, Wagner

; Fontana, Nicolò ; Falk, Alexander ; Schreiner, Simon H. F. ; Gramüller, Johannes ; Scrimgeour, Alexander ; Gschwind, Ruth M.

; Horinek, Dominik

; Nuernberger, Patrick

; Bauer, Jonathan O.

License: Creative Commons Attribution 4.0
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Date of publication of this fulltext: 13 Feb 2025 05:48

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Abstract

Aminophosphates are the focus of research on prebiotic phosphorylation chemistry. Their bifunctional nature also makes them a powerful class of organocatalysts. However, the structural chemistry and dynamics of proton-binding in phosphorylation and organocatalytic mechanisms are still not fully understood. Aminophosphine chalcogenides, preserving the H2N–P+–Ch− structural motif, represent ...