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Reductive Coupling Synthesis of a Soluble Poly(9,10-anthrylene ethynylene)

URN to cite this document:
urn:nbn:de:bvb:355-epub-752061
DOI to cite this document:
10.5283/epub.75206
Geisler, Isabell ; Forster, Michael ; Misimi, Bujamin ; Schedlbauer, Jakob ; Riedl, Thomas ; Lupton, John M. ; Scherf, Ullrich
[img]License: Creative Commons Attribution 4.0
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Date of publication of this fulltext: 11 Mar 2025 12:19



Abstract

A fully soluble poly(9,10-anthrylene ethynylene), poly[2,6-(2-octyldecyl)-9,10-anthrylene ethynylene] PAAE, with moderate degrees of polymerization Pn of ca. 10 is generated in a reductive, dehalogenative homocoupling scheme, starting from a 2,6-dialkylated 9,10-bis(dibromomethylene)-9,10-dihydroanthracene monomer and n-BuLi/CuCN as the reducing agent. PAAE shows surprisingly broad and ...

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