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Sivan, Yonatan ; Un, Ieng Wai ; Kalyan, Imon ; Lin, Kai-Qiang ; Lupton, John M. ; Bange, Sebastian

Crossover from Nonthermal to Thermal Photoluminescence from Metals Excited by Ultrashort Light Pulses

Sivan, Yonatan, Un, Ieng Wai, Kalyan, Imon, Lin, Kai-Qiang , Lupton, John M. and Bange, Sebastian (2023) Crossover from Nonthermal to Thermal Photoluminescence from Metals Excited by Ultrashort Light Pulses. ACS Nano 17 (12), pp. 11439-11453.

Date of publication of this fulltext: 11 Mar 2025 13:33
Article
DOI to cite this document: 10.5283/epub.75215


Abstract

Photoluminescence from metal nanostructures following intense ultrashort illumination is a fundamental aspect of light–matter interactions. Surprisingly, many of its basic characteristics are under ongoing debate. Here, we resolve many of these debates by providing a comprehensive theoretical framework that describes this phenomenon and support it by an experimental confirmation. Specifically, we ...

Photoluminescence from metal nanostructures following intense ultrashort illumination is a fundamental aspect of light–matter interactions. Surprisingly, many of its basic characteristics are under ongoing debate. Here, we resolve many of these debates by providing a comprehensive theoretical framework that describes this phenomenon and support it by an experimental confirmation. Specifically, we identify aspects of the emission that are characteristic to either nonthermal or thermal emission, in particular, differences in the spectral and electric field dependence of these two contributions to the emission. Overall, nonthermal emission is characteristic of the early stages of light emission, while the later stages show thermal characteristics. The former dominate only for moderately high illumination intensities for which the electron temperature reached after thermalization remains close to room temperature.



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Details

Item typeArticle
Journal or Publication TitleACS Nano
Publisher:American Chemical Society (ACS)
Open Access Type:No Open Access
Volume:17
Number of Issue or Book Chapter:12
Page Range:pp. 11439-11453
Date8 June 2023
InstitutionsPhysics > Institute of Experimental and Applied Physics > Chair Professor Lupton > Group John Lupton
Identification Number
ValueType
10.1021/acsnano.3c01016DOI
Keywordsplasmonics, electron nonequilibrium, photoluminescence, thermo-optic effects, metal nanoparticles
Dewey Decimal Classification500 Science > 530 Physics
StatusPublished
RefereedYes, this version has been refereed
Created at the University of RegensburgPartially
Item ID75215

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