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Scholtes, Christian Léonard ; Ilgen, Julian ; Gschwind, Ruth M.

Efficient detection of 1H, 15N correlations in hydrogen bonded low molecular catalyst–substrate intermediates without selective 15N-labelling

Scholtes, Christian Léonard , Ilgen, Julian and Gschwind, Ruth M. (2025) Efficient detection of 1H, 15N correlations in hydrogen bonded low molecular catalyst–substrate intermediates without selective 15N-labelling. Chemical Communications.

Date of publication of this fulltext: 14 Apr 2025 08:24
Article
DOI to cite this document: 10.5283/epub.76571


Abstract

To date, SOFAST approaches have generally been limited to biomolecules. We present the applicability of SOFAST-HMQC techniques to small molecules in the slow-tumbling regime offering a time-efficient characterization of catalyst substrate hydrogen bonds with nitrogen at natural abundance. This extends NMR access to a broader range of catalyst substrate combinations.



Involved Institutions


Details

Item typeArticle
Journal or Publication TitleChemical Communications
Publisher:Royal Society of Chemistry (RSC)
Date11 April 2025
InstitutionsChemistry and Pharmacy > Institut für Organische Chemie > Arbeitskreis Prof. Dr. Ruth Gschwind
Projects
Funded by: Deutsche Forschungsgemeinschaft (DFG) (426795949)
Funded by: Deutsche Forschungsgemeinschaft (DFG) (444632635)
Identification Number
ValueType
10.1039/D5CC00537JDOI
Dewey Decimal Classification500 Science > 540 Chemistry & allied sciences
StatusPublished
RefereedYes, this version has been refereed
Created at the University of RegensburgYes
URN of the UB Regensburgurn:nbn:de:bvb:355-epub-765711
Item ID76571

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