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Green-light Cerium Photocatalysis enabled by Pyridine N-oxide Ligands
Müller, Nicolas
, Stahl, Jessica, Stoiber, Julia and König, Burkhard
(2025)
Green-light Cerium Photocatalysis enabled by Pyridine N-oxide Ligands.
European Journal of Organic Chemistry.
Date of publication of this fulltext: 04 Jun 2025 07:55
Article
DOI to cite this document: 10.5283/epub.76764
This is the latest version of this item.
Abstract
Pyridine N-oxides are reported as neutral ligands in cerium photocatalysis. By using those neutral ligands, photoactive Ce(IV)-species are generated, which show an extensive bathochromic shift compared to previously employed cerium-based complexes. This allows the effective utilization of green light in the redox-neutral CH-hydrazination of small molecules under very mild photocatalytic conditions.
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| Item type | Article | ||||
| Journal or Publication Title | European Journal of Organic Chemistry | ||||
| Publisher: | Wiley | ||||
|---|---|---|---|---|---|
| Date | 29 April 2025 | ||||
| Institutions | Chemistry and Pharmacy > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König | ||||
| Projects |
Funded by:
Deutsche Forschungsgemeinschaft (DFG)
(444632635)
| ||||
| Identification Number |
| ||||
| Keywords | cerium · LMCT · N-oxides · photocatalysis · radicals | ||||
| Dewey Decimal Classification | 500 Science > 540 Chemistry & allied sciences | ||||
| Status | Published | ||||
| Refereed | Yes, this version has been refereed | ||||
| Created at the University of Regensburg | Yes | ||||
| URN of the UB Regensburg | urn:nbn:de:bvb:355-epub-767649 | ||||
| Item ID | 76764 |
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