PCET beyond Simple pKa-Related Base Effects: Unlocking Inaccessible Substrates for Direct Intermolecular Photocatalytic Ring-Opening Remote Alkylative C-C Functionalization of Cycloalkanols Version 2

URN to cite this document:: urn:nbn:de:bvb:355-epub-772499
DOI to cite this document:: 10.5283/epub.77249

Klimkait, Michael ; Berg, Nele ; Gschwind, Ruth M.

; Zeitler, Kirsten

License: Creative Commons Attribution Non-commercial No Derivatives 4.0
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Date of publication of this fulltext: 23 Jul 2025 06:53

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Abstract

Oxidative multisite proton-coupled electron transfer (MS-PCET) reactions, particularly those occurring under metal-free pho¬to¬catalytic conditions using visible light, have emerged as a promising tool for the activation of strong O-H bonds in (cyclo)alkanols. However, these methods generally require the use of e-rich arene-containing derivatives (para-methoxyphenyl (PMP), etc.) – a factor that ...