Icosahedral Clusters [In@Tr12]10–: Synthesis, Characterization, and Electronic Structure Investigations of Na4A6Tr13 (A = Rb, Cs; Tr = In, Tl)

URN to cite this document:: urn:nbn:de:bvb:355-epub-777578
DOI to cite this document:: 10.5283/epub.77757

Janesch, Melissa ; Karttunen, Antti J. ; Gärtner, Stefanie

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Date of publication of this fulltext: 18 Sep 2025 05:32

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Abstract

While thallium forms several clusters in alkali metal thallides, indium clusters in related alkali metal indides are very rare. Here the mixing of the heavy trielides indium and thallium to approximate icosahedral entities present in Na4A6Tr13 (A = K, Rb, Cs; Tr = In, Tl) is reported. Experimental results prove that at least up to 76% indium can be introduced in this structure type. From the ...