Coordination Studies of a Triazole‐Substituted 3H‐1,2,4‐Diazaphosphole: C―C and C―N Bond Activation Induced by Cobalt(0) and Nickel(0) Complexes

URN to cite this document:: urn:nbn:de:bvb:355-epub-780718
DOI to cite this document:: 10.5283/epub.78071

Hauer, Sebastian

; Balázs, Gábor

; Reitz, Justus ; Hansmann, Max M. ; Wolf, Robert

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Date of publication of this fulltext: 18 Nov 2025 06:52

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Abstract

The reactivity of the recently reported 3H-1,2,4-diazaphosphole 1 toward electron-rich Ni and Co complexes is described. Compound 1 reacts with [Ni(cod)2] (cod = 1,5-cyclooctadiene) to afford complex 2, which features a 1,2,3-triazole-4-ylidene-type carbene ligand derived from the cleavage of the C―C(Ph) bond in 1. In contrast, [(IPr)Ni(vtms)2] induces N―C(iPr) bond cleavage of the 1,2,3-triazole ...