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Synthesis of rigidified flavin–guanidinium ion conjugates and investigation of their photocatalytic properties

Schmaderer, Harald ; Bhuyan, Mouchumi ; König, Burkhard



Abstract

Flavin chromophores can mediate redox reactions upon irradiation by blue light. In an attempt to increase their catalytic efficacy, flavin derivatives bearing a guanidinium ion as oxoanion binding site were prepared. Chromophore and substrate binding site are linked by a rigid Kemp’s acid structure. The molecular structure of the new flavins was confirmed by an X-ray structure analysis and their ...

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