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Tris(2-pyridyl)methan-Derivate mit chiralem Brückenatom - Liganden, Komplexe, Katalysen

URN to cite this document:
urn:nbn:de:bvb:355-opus-385
Maier, Reinhard J.
Date of publication of this fulltext: 05 Sep 2001 10:46


Abstract (German)

Zwei unterschiedliche Reihen von C1-symmetrischen Tris(2-pyridyl)methan- Dreibeinliganden mit Pyridin-2-yl-, 6-Phenylpyridin-2-yl- und 6-Methoxy- oder 6-Menthyloxypyridin-2-yl-Substituenten wurden synthetisiert. Die Menthyloxyderivate wurden mittels Chromatographie hinsichtlich der Konfiguration am verbrückenden Kohlenstoffatom getrennt. Die Reaktion mit CuCl2 und RhCl3 lieferte ...

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Translation of the abstract (English)

Two different series of C1-symmetric tris(2-pyridyl)methane tripod ligands were synthesized with pyridin-2-yl, 6-phenylpyridin-2-yl and 6-methoxy- or 6-menthyloxypyridin-2-yl substitutents. The menthoxy devivatives were resolved with respect to the bridging carbon atom by chromatography. In reactions with CuCl2 and RhCl3 complexes were obtained which could be analyzed by X-ray ...

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