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Tris(2-pyridyl)methan-Derivate mit chiralem Brückenatom - Liganden, Komplexe, Katalysen

Maier, Reinhard J. (2001) Tris(2-pyridyl)methan-Derivate mit chiralem Brückenatom - Liganden, Komplexe, Katalysen. PhD, Universität Regensburg.

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Date of publication of this fulltext: 05 Sep 2001 10:46

Abstract (German)

Zwei unterschiedliche Reihen von C1-symmetrischen Tris(2-pyridyl)methan- Dreibeinliganden mit Pyridin-2-yl-, 6-Phenylpyridin-2-yl- und 6-Methoxy- oder 6-Menthyloxypyridin-2-yl-Substituenten wurden synthetisiert. Die Menthyloxyderivate wurden mittels Chromatographie hinsichtlich der Konfiguration am verbrückenden Kohlenstoffatom getrennt. Die Reaktion mit CuCl2 und RhCl3 lieferte ...


Translation of the abstract (English)

Two different series of C1-symmetric tris(2-pyridyl)methane tripod ligands were synthesized with pyridin-2-yl, 6-phenylpyridin-2-yl and 6-methoxy- or 6-menthyloxypyridin-2-yl substitutents. The menthoxy devivatives were resolved with respect to the bridging carbon atom by chromatography. In reactions with CuCl2 and RhCl3 complexes were obtained which could be analyzed by X-ray ...


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Item type:Thesis of the University of Regensburg (PhD)
Date:4 September 2001
Referee:Henri Brunner
Date of exam:16 May 2001
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Henri Brunner
Keywords:Ligand, Chiralität <Chemie>, Metallchelate / Chirale Verbindungen, Konfiguration <Chemie>, , ortho-Metallierung, Dreibeinligand, Asymmetrische Katalyse, Metallchiralität , Chiral tripod ligands, ortho-metallation, absolute configuration
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Item ID:9883
Owner only: item control page


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