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Luminescent Metal-Ligand Complexes as Labels for Polarization Immunoassays and for Determination of Hydrogen Peroxide

URN to cite this document:
urn:nbn:de:bvb:355-opus-881
DOI to cite this document:
10.5283/epub.9932
Dürkop, Axel
Date of publication of this fulltext: 10 Jul 2002 13:41


Abstract (German)

Es wurden zwei Ruthenium Metall-Liganden Komplexe synthetisiert, die entweder 5-carboxy-2,2�-bipyridin oder 5,5�-dicarboxy-2,2�-bipyridin als asymmetrischen Liganden enthalten. Die Absorptionsmaxima sind um 450 nm und die Emissionsmaxima sind bei 675 nm und 705 nm. Die Emissionsmaxima werden bis zu 30 nm rotverschoben, wenn der Komplex kovalent an ein Protein gebunden ist. Die ...

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Translation of the abstract (English)

Two metal-ligand complexes were synthesized containing 5-carboxy-2,2� -bipyridine and 5,5�-dicarboxy-2,2�-bipyridine as the asymmetric ligand. The absorption maxima were found to be around 450 nm and the emission maxima are 675 nm and 705 nm, respectively. The fundamental polarization values were 0.33 for [Ru(2,2�-bipyridine)2(5,5�-dicarboxy-2,2�-bipyridine)](PF6)2 and 0.18 for ...

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