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Asymmetrisch substituierte 1,1´-Binaphthyle. - Synthese, Komplexe und enantioselektive Katalyse -

URN to cite this document:
urn:nbn:de:bvb:355-opus-1117
Weber, Matthias
Date of publication of this fulltext: 16 Oct 2002 13:44


Abstract (German)

Dargestellt wurden enantiomerenreine 1,1´-Binaphthylverbindungen mit unterschiedlichen Substituenten in 2- und 2´-Position. Durch Schiff-Basenkondensation von 2-Amino-2´-methoxy-1,1´-binaphthyl ((S)-NOMBIN) oder 2-Amino-2´-hydroxy-1,1´-binaphthyl ((S)-NOBIN) mit den Aldehyden Salicylaldehyd, 2-Pyridinaldehyd und 2-(Formylphenyl)diphenylphosphan wurden unterschiedliche zwei- und dreizähnige ...

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Translation of the abstract (English)

A variety of 1,1´-binaphthyl derivatives with different substituents in 2- and 2´-position were synthesized. Different types of ligands are obtained by the reaction of 2-amino-2´methoxy-1,1´-binaphthyl ((S)-NOMBIN) or 2-amino-2´-hydroxy-1,1´-binaphthyl ((S)-NOBIN) with salicylaldehyde, 2-pyridinecarbaldehyde and 2-formylphenyl(diphenyl)phosphine. Complexes with a chiral metal atom are formed with ...

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