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Korytár, Richard ; Evers, Ferdinand

Current-induced mechanical torque in chiral molecular rotors

Korytár, Richard und Evers, Ferdinand (2023) Current-induced mechanical torque in chiral molecular rotors. Beilstein J. Nanotechnol. 14, S. 711-721.

Veröffentlichungsdatum dieses Volltextes: 09 Jan 2023 06:55
Artikel
DOI zum Zitieren dieses Dokuments: 10.5283/epub.53487


Zusammenfassung

There has been great endeavor to engineer molecular rotors operated by an electrical current. A frequently met operation principle is the transfer of angular momentum taken from the incident flux. In this paper, we present an alternative driving agent that works also in situations where angular momentum of the incoming flux is conserved. This situation arises typically with molecular rotors that ...

There has been great endeavor to engineer molecular rotors operated by an electrical current. A frequently met operation principle is the transfer of angular momentum taken from the incident flux. In this paper, we present an alternative driving agent that works also in situations where angular momentum of the incoming flux is conserved. This situation arises typically with molecular rotors that exhibit an easy axis of rotation. For quantitative analysis we investigate here a classical model where molecule and wires are represented by a rigid curved path. We demonstrate that in the presence of chirality, the rotor generically undergoes a directed motion, provided that the incident current exceeds a threshold value. Above this threshold, the corresponding rotation frequency (per incoming particle current) for helical geometries turns out to be 2 & pi;m/M1, where m/M1 is the ratio of the mass of an incident charge carrier and the mass of the helix per winding number.



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Details

DokumentenartArtikel
Titel eines Journals oder einer ZeitschriftBeilstein J. Nanotechnol.
Verlag:BEILSTEIN-INSTITUT
Ort der Veröffentlichung:FRANKFURT AM MAIN
Band:14
Seitenbereich:S. 711-721
Datum12 Juni 2023
InstitutionenPhysik > Institut für Theoretische Physik > Lehrstuhl Ferdinand Evers
Identifikationsnummer
WertTyp
10.3762/bjnano.14.57DOI
https://doi.org/10.3762/bjnano.14.57URN
Stichwörter / KeywordsMOTORS; molecular junctions; molecular motors; molecular switches
Dewey-Dezimal-Klassifikation500 Naturwissenschaften und Mathematik > 530 Physik
StatusVeröffentlicht
BegutachtetJa, diese Version wurde begutachtet
An der Universität Regensburg entstandenJa
URN der UB Regensburgurn:nbn:de:bvb:355-epub-534873
Dokumenten-ID53487

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