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Karl, Tobias A. ; Seidl, Max ; König, Burkhard

Energy Harvesting: Synthetic Use of Recovered Energy in Electrochemical Late-Stage Functionalization

Artikel

Karl, Tobias A. , Seidl, Max und König, Burkhard (2023) Energy Harvesting: Synthetic Use of Recovered Energy in Electrochemical Late-Stage Functionalization. ChemElectroChem, e202201097.

DOI zum Zitieren dieses Dokuments: 10.5283/epub.53789

Dies ist die aktuelle Version dieses Eintrags.


Zusammenfassung

An induction-based energy harvesting (EH) device was presented. It converted part of the rotational energy of magnetic stirrers back into electrical energy, making it accessible for electrochemical transformations. After rectification, the induced AC voltage was optionally provided as a constant voltage or constant current whereby the available voltage could directly be adjusted by the stirring ...

An induction-based energy harvesting (EH) device was presented. It converted part of the rotational energy of magnetic stirrers back into electrical energy, making it accessible for electrochemical transformations. After rectification, the induced AC voltage was optionally provided as a constant voltage or constant current whereby the available voltage could directly be adjusted by the stirring rate of the reaction. The comparability of the results with reactions carried out with commercial power supplies has been demonstrated on six different late-stage functionalization, including methylation, carboxylation, trifluoromethylation, imidation, hydrolysis, and keto-olefin coupling. Therefore, the described EH device is a low-cost, resource-efficient alternative to a commercial electrochemical set-up and enables laboratories without specialized equipment to perform electrochemical reactions.



Beteiligte Einrichtungen


Details

DokumentenartArtikel
Titel eines Journals oder einer ZeitschriftChemElectroChem
VerlagWiley
Open Access ArtDEAL (Wiley Gold)
Seitenbereiche202201097
Datum13 Januar 2023
Veröffentlichungsdatum15 Feb 2023 12:50
InstitutionenChemie und Pharmazie > Institut für Organische Chemie > Lehrstuhl Prof. Dr. Burkhard König
Identifikationsnummer
WertTyp
10.1002/celc.202201097DOI
Stichwörter / KeywordsElectrochemistry · Energy harvesting · Late-stage functionalization · Radicals · Self-sustaining
Dewey-Dezimal-Klassifikation500 Naturwissenschaften und Mathematik > 540 Chemie
StatusVeröffentlicht
BegutachtetJa, diese Version wurde begutachtet
An der Universität Regensburg entstandenJa
URN der UB Regensburgurn:nbn:de:bvb:355-epub-537895
Dokumenten-ID53789

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