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Reaction of Iodoform and Isopropyl Grignard Reagent Revisited

Hoffmann, R. W. and Müller, M. and Menzel, K. and Gschwind, R. M. and Schwerdtfeger, P. and Malkina, O. L. and Malkin, V.G. (2001) Reaction of Iodoform and Isopropyl Grignard Reagent Revisited. Organometallics 20 (25), pp. 5310-5313.

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A new long-lived intermediate has been identified in the reaction of iodoform (1) with isopropylmagnesium chloride at −78 °C. The structure of the symmetrical iodine ate complex 7, I2CH−I−CHI2-MgCl+, has been assigned to the deep red intermediate by NMR spectroscopic techniques, supported by calculations of 1JC-H, 2JC-C, and 3JC-H coupling constants.

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Item Type:Article
Institutions:Chemistry and Pharmacy > Institut für Organische Chemie > Arbeitskreis Prof. Dr. Ruth Gschwind
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Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:No
Deposited On:11 Nov 2009 17:15
Last Modified:11 Nov 2009 17:15
Item ID:10646
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