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Photochemistry of Tetrasulfido Complexes of Molybdenum(VI), Tungsten(VI), Vanadium(V) and Rhenium(VII)

Vogler, Arnd and Kunkely, Horst (1988) Photochemistry of Tetrasulfido Complexes of Molybdenum(VI), Tungsten(VI), Vanadium(V) and Rhenium(VII). Inorganic Chemistry 27 (3), pp. 504-507.

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Abstract

The tetrasulfido complexes [MoS4]2-, [WS4]2-, [VS4]3-, and [ReS4]- photolyze in solution in the presence of air according to the stoichiometry [MS4]n- + 02 -> [M02S2]n- + S2. The diatomic sulfur can be scavenged by norbornadiene or tetramerizes to yield stable S8. Quantum yields are strongly wavelength-dependent. For all complexes the reactive excited states are of the ligand to metal charge transfer type.


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Item Type:Article
Date:1988
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Alumni or Retired Professors > Prof. Dr. Arnd Vogler
Identification Number:
ValueType
10.1021/ic00276a014DOI
Dewey Decimal Classification:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Deposited On:16 Mar 2010 05:55
Last Modified:13 Mar 2014 13:04
Item ID:13363
Owner Only: item control page

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