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Photochemistry of Tetrasulfido Complexes of Molybdenum(VI), Tungsten(VI), Vanadium(V) and Rhenium(VII)

Vogler, Arnd and Kunkely, Horst (1988) Photochemistry of Tetrasulfido Complexes of Molybdenum(VI), Tungsten(VI), Vanadium(V) and Rhenium(VII). Inorganic Chemistry 27 (3), pp. 504-507.

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Abstract

The tetrasulfido complexes [MoS4]2-, [WS4]2-, [VS4]3-, and [ReS4]- photolyze in solution in the presence of air according to the stoichiometry [MS4]n- + 02 -> [M02S2]n- + S2. The diatomic sulfur can be scavenged by norbornadiene or tetramerizes to yield stable S8. Quantum yields are strongly wavelength-dependent. For all complexes the reactive excited states are of the ligand to metal charge ...

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Item Type:Article
Date:1988
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Emeriti > Prof. Dr. Arnd Vogler
Identification Number:
ValueType
10.1021/ic00276a014DOI
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Owner: Universitätsbibliothek Regensburg
Deposited On:16 Mar 2010 05:55
Last Modified:13 Mar 2014 13:04
Item ID:13363
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