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Photochemical reductive elimination of hexabromotellurate(IV)

Vogler, Arnd and Paukner, A. (1989) Photochemical reductive elimination of hexabromotellurate(IV). Journal of Photochemistry and Photobiology A Chemistry 46 (2), pp. 227-231.

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In the region between 500 nm and 300 nm the electronic spectrum of [TeBr6]2− displays absorptions which are assigned to s → p transitions. At shorter wavelengths ligand-to-metal charge transfer (LMCT) bands appear. Irradiation of [TeBr6]2− in acetonitrile led to a reductive elimination according to the equation [TeBr6]2− → [TeBr4]2− + Br2. Upon LMCT excitation (λirr = 254 nm) the quantum yield ...


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Item Type:Article
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Emeriti > Prof. Dr. Arnd Vogler
Identification Number:
10.1016/1010-6030(89)80008-5 DOI
Subjects:500 Science > 540 Chemistry & allied sciences
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Owner: Universitätsbibliothek Regensburg
Deposited On:16 Mar 2010 05:52
Last Modified:13 Mar 2014 13:04
Item ID:13368
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