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Photoredox reaction of a trinuclear Co(III), Co(III), Ru(II) complex induced by metal-to-metal charge transfer excitation and a subsequent charge shift

Kunkely, Horst and Vogler, Arnd (1993) Photoredox reaction of a trinuclear Co(III), Co(III), Ru(II) complex induced by metal-to-metal charge transfer excitation and a subsequent charge shift. Inorganica Chimica Acta 209 (1), pp. 93-95.

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Abstract

The trinuclear complex (NH3)5CoIII(μ-NC)CoIII(CN)4(μ-CN)RuII(CN)53− shows a long wavelength absorption near 370 nm which is assigned to a metal-to-metal charge transfer (MMCT) transition from Ru(II) to the central Co(III) ion. Light absorption by this bands leads to a redox decomposition: (NH3)5CoIII(CN)4(μ-CN)RuII(CN)53−→5NH3+ Co2++CoIII(CN)63−+ RuIII(CN)5H2O2−. It is suggested that the initial ...

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Item Type:Article
Date:1993
Institutions:Chemistry and Pharmacy > Institut für Anorganische Chemie > Emeriti > Prof. Dr. Arnd Vogler
Identification Number:
ValueType
10.1016/S0020-1693(00)84986-5 DOI
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Yes
Owner: Universitätsbibliothek Regensburg
Deposited On:17 Mar 2010 09:03
Last Modified:13 Mar 2014 13:06
Item ID:13565
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