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Synthese und Hofmann-Abbau des 1-(Diphenyl-hydroxymethyl)-2,2-dimethyl-6,7-dimethoxy-1,2,3,4-tetrahydroisochinolinium-Ions

Wiegrebe, Wolfgang and Rohrbach-Munz, B. and Awe, W. and Kirk, O. (1975) Synthese und Hofmann-Abbau des 1-(Diphenyl-hydroxymethyl)-2,2-dimethyl-6,7-dimethoxy-1,2,3,4-tetrahydroisochinolinium-Ions. Helvetica Chimica Acta 58 (6), pp. 1825-1833.

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Abstract

Summary. The synthesis of the N-quaternary aminoalcohol 6 is described. Analogous to the aminoalcohols 1 and 2, 6 on treatment w i t h alkali undergoes fission of the substituent at C(l) as a carbonyl compound, with formation of a N, N-dimethyl-l,2,3,4-tetrahydroisoquinolinium ion, which is further degraded to the corresponding o-vinyl-benzylamine {Scheme 7). - As a by-product of a ...

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Item Type:Article
Date:1975
Institutions:Chemistry and Pharmacy > Institute of Pharmacy > Retired Professors > Prof. Wiegrebe
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Unknown
Owner: Universitätsbibliothek Regensburg
Deposited On:22 Jun 2010 06:21
Last Modified:13 Mar 2014 13:38
Item ID:15447
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