Donges, D. and Nagle, J. K. and Yersin, Hartmut (1997) Characterization of intraligand charge transfer transitions in Pd(qol)₂, Pt(qol)₂, and Pt(qtl)₂ investigated by Shol'skii spectroscopy. Journal of Luminescence 72-74, pp. 658-659.
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Pd(qol)₂,Pt(qol)₂ and Pt(qtl)₂ are investigated in n-octane Shpol’skii matrices at T = 1.2 K. For the first time, it is possible to obtain highly resolved phosphorescence and triplet as well as singlet excitation spectra. The corresponding excited states are assigned to intraligand charge transfer (ILCT) transitions. Their characteristic electronic and vibrational properties are studied in detail.
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|Institutions:||Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry III - Physical Chemistry (Light and Matter) > Prof. Dr. Hartmut Yersin|
|Keywords:||Shpol'skii spectroscopy; Intraligand charge transfer; Platinum metal compounds; Spin polarization|
|Subjects:||500 Science > 540 Chemistry & allied sciences|
|Refereed:||Yes, this version has been refereed|
|Created at the University of Regensburg:||Partially|
|Deposited On:||14 Feb 2011 12:37|
|Last Modified:||14 Feb 2011 12:37|