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Zero-field splittings of the two lowest excited electronic states in crystalline [Ru(bpy)₃]X₂ with X = PF₆, ClO₄

Yersin, Hartmut ; Gallhuber, E. ; Hensler, G. ; Schweitzer, D.



Zusammenfassung

For the title compounds zero-magnetic field ODMR signals have been observed on the zero-phonon lines which correspond to the two lowest excited states and which result from Ru4d —› bpyπ* charge-transfer transitions. The splitting into sublevels are of the order of 0.1 cm⁻¹ and the corresponding electronic states may be classified as doubly degenerate on the basis of the usual resolution of the ...

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