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Cytostatic compounds. VII. Effect of aldimine structure on the N,N'-dialkyl-alpha ,alpha '-diphenylethylenediamine-benzylalkylamine ratio formed in the reduction of benzylidenealkylamines with activated aluminum

Schönenberger, Helmut and Thies, Heinrich and Rappl, A. (1967) Cytostatic compounds. VII. Effect of aldimine structure on the N,N'-dialkyl-alpha ,alpha '-diphenylethylenediamine-benzylalkylamine ratio formed in the reduction of benzylidenealkylamines with activated aluminum. Archiv der Pharmazie und Berichte der Deutschen Pharmazeutischen Gesellschaft 300 (6), pp. 483-491.

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Abstract

cf. CA 67: 21262k. The formation of the dimeric redn. product was found to be affected by the stability of the intermediate radical which is related to the number of possible mesomeric structures of the aldimine (Schiff's base) and to the concn. of the reaction soln. [TABLE OMITTED] The observed reaction route (% dimer formed) by redn. of 0.025 mole Schiff base with 0.075 mole Al and 200 mg. ...

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Item Type:Article
Date:1967
Additional information (public):CAN 67:116678 25 Noncondensed Aromatic Compounds 1775-75-3P; 2298-58-0P; 3910-55-2P; 3910-57-4P; 3910-58-5P; 4589-09-7P; 7020-93-1P; 7173-86-6P; 16181-47-8P; 16181-49-0P; 16183-19-0P; 16183-21-4P; 16183-22-5P; 16183-23-6P; 16183-25-8P; 16183-27-0P; 16183-28-1P; 16183-29-2P; 16183-30-5P; 16183-31-6P; 16183-32-7P; 16183-34-9P; 16183-35-0P; 16183-36-1P; 16183-37-2P; 16183-38-3P; 16183-39-4P; 16183-40-7P; 16183-41-8P; 16183-42-9P; 16183-44-1P; 16216-75-4P Role: SPN (Synthetic preparation), PREP (Preparation) (prepn. of)
Institutions:Chemistry and Pharmacy > Institute of Pharmacy > Retired Professors > Prof. Schönenberger
Identification Number:
ValueType
1967:516678Other
Keywords:ALDIMINES CYTOSTATIC ETHYLENEDIAMINES ETHYLENEDIAMINES CYTOSTATIC
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Unknown
Owner: Petra Gürster
Deposited On:19 Nov 2010 08:20
Last Modified:19 Nov 2010 08:20
Item ID:18188
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