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Reactions of Schiff bases. XI. Effect of heavy metal halides on the reaction between Grignard-type compounds and Schiff bases

Thies, H. and Schönenberger, Helmut and Zeller, A. (1965) Reactions of Schiff bases. XI. Effect of heavy metal halides on the reaction between Grignard-type compounds and Schiff bases. Archiv der Pharmazie und Berichte der Deutschen Pharmazeutischen Gesellschaft 298 (1), pp. 26-33.

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Abstract

cf. CA 54, 18432c; 55, 18634c; 56, 363a. The reaction between benzylidenebutylamine (I) with the Grignard reagent iso-PrMgBr2 was used as model reaction to study the influence of heavy metal halides on products and yield. Without any metal halide addn., the reaction products were chiefly alpha -phenyl-alpha -butylamino-beta -methylpropane (II) and some benzylbutylamine (III) as a monomeric redn. ...

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Item Type:Article
Date:1965
Additional information (public):CAN 62:74285 39 Organometallic and Organometalloidal Compounds 4169-62-4; 6867-97-6 (Derived from data in the 7th Collective Formula Index (1962-1966); 7439-95-4 (Magnesium) (compds., alkyl halo, reaction with alkyl halides, catalysts and); 1137-52-6P (Benzylamine, N-butyl-alpha -isopropyl-); 2403-22-7P (Benzylamine, N-butyl-) Role: PREP (Preparation) (formation from N-benzylidenebutylamine and isopropylmagnesium halides); 1165-52-2P (Ethylenediamine, N,N'-dibutyl-1,2-diphenyl-, meso-) Role: PREP (Preparation) (formation in N-benzylidenebutylamine reaction with isopropylmagnesium halides); 109-73-9P (Butylamine) Role: PREP (Preparation) (formation of, in N-benzylidenebutylamine reaction with isopropylmagnesium halides); 7705-07-9 (Titanium chloride, TiCl3) (in N-benzylidenebutylamine reaction with isopropylmagnesium halides); 1077-18-5 (Butylamine, N-benzylidene-) (reaction with isopropylmagnesium halides in presence of transition metal halides); 920-39-8 (Magnesium, bromoisopropyl-); 1068-55-9 (Magnesium, chloroisopropyl-); 1068-56-0 (Magnesium, iodoisopropyl-) (reaction with N-benzylidenebutylamine in presence of transition metal halides); 7446-70-0 (Aluminum chloride); 7447-39-4 (Copper chloride, CuCl2); 7487-94-7 (Mercury chloride, HgCl2); 7646-79-9 (Cobalt chloride, CoCl2); 7646-85-7 (Zinc chloride); 7705-08-0 (Iron chloride, FeCl3); 7718-54-9 (Nickel chloride, NiCl2); 7718-98-1 (Vanadium chloride, VCl3); 7758-95-4 (Lead chloride, PbCl2); 7773-01-5 (Manganese chloride, MnCl2); 10025-73-7 (Chromium chloride, CrCl3); 10043-52-4 (Calcium chloride) (N-benzylidenebutylamine reaction with isopropylmagnesium halides in presence of)
Institutions:Chemistry and Pharmacy > Institute of Pharmacy > Retired Professors > Prof. Schönenberger
Identification Number:
ValueType
1965:74285Other
Keywords:Schiff bases (Grignard reaction of, in presence of transition metal halides) Transition metal halides (Grignard reaction with Schiff bases in presence of) Grignard reaction (with Schiff bases in presence of transition metal halides)
Subjects:500 Science > 540 Chemistry & allied sciences
Status:Published
Refereed:Yes, this version has been refereed
Created at the University of Regensburg:Unknown
Owner: Petra Gürster
Deposited On:18 Nov 2010 11:09
Last Modified:18 Nov 2010 11:13
Item ID:18215
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