Yersin, Hartmut and Hidvegi, I. and Gliemann, G. and Stock, M. (1979) Transition energy tuning from 3.3 - 1.4 eV in the system Mx[Pt(CN)₄]•mH₂O. Physical Review B (PRB) 19, pp. 177-180.
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The electronic transition energies of the Mx[Pt²⁺(CN)₄]•mH₂O compounds, crystallizing in columnar structures, depend strongly on the Pt-Pt distance R in the direction of the columns. R can be varied by substituting M and/or by application of high pressure. Using three different compounds and applying hydrostatic pressures up to 38 kbar it is possible to adjust the emission energy continously from 3.3 to about 1.35 eV. The pressure-induced energy shift is unusually large with values between -320 and -140 cm⁻¹/kbar.
|Institutions:||Chemistry and Pharmacy > Institut für Physikalische und Theoretische Chemie > Chair of Chemistry III - Physical Chemistry (Light and Matter) > Prof. Dr. Hartmut Yersin|
|Subjects:||500 Science > 540 Chemistry & allied sciences|
|Refereed:||Yes, this version has been refereed|
|Created at the University of Regensburg:||Yes|
|Owner:||Prof. Dr. Hartmut Yersin|
|Deposited On:||24 Feb 2011 12:39|
|Last Modified:||24 Feb 2011 12:39|